Home | english  | Impressum | Datenschutz | Sitemap | KIT

Publications 2015

Pyrolysis of ethanol: A shock-tube/TOF-MS and modeling study
Johannes Kiecherer, Cornelie Bänsch, Tobias Bentz, Matthias Olzmann
Proc. Combust. Inst. (2015), 35, 465-472, DOI: 10.1016/j.proci.2014.05.086 [abstract ]

Kinetics of the Reactions of Hydroxyl Radicals with Diacetylene and Vinylacetylene
Jörg Sommerer, Matthias Olzmann
Z. Phys. Chem. (2015), 229, 495-505, DOI: 10.1515/zpch-2014-0618 [abstract ]

The reactions of N-methylformamide and N,N-dimethylformamide with OH and their photo-oxidation under atmospheric conditions: experimental and theoretical studies.
Arne-Joakim C. Bunkan, Jens Hetzler, Thomáš Mikoviny, Armin Wisthaler, Claus J. Nielsen, and Matthias Olzmann
Phys. Chem. Chem. Phys. (2015), 17, 7046-7059, Open Access DOI: 10.1039/C4CP05805D [abstract ]

Einfluss der Temperatur in der Nachbrennkammer von Kremationsöfen auf die CO-Konzentration im Abgas
Jörg Bachmann, Johannes Kiecherer, Jörg Sommerer, and Matthias Olzmann
Gefahrstoffe-Reinhaltung der Luft. (2015), 17, 7046-7059, www.gefahrstoffe.de [PDF ]

Thermal Decomposition of NCN: Shock-Tube Study, Quantum Chemical Calculations, and Master-Equation Modeling
Anna Busch, Núria González-García, György Lendvay, and Matthias Olzmann
J. Phys. Chem. A. (2015), 119 (28), 7838-7846, DOI: 10.1021/acs.jpca.5b01347 [abstract ]

Acceleration of Long-Range Photoinduced Electron Transfer through DNA by Hydroxyquinolines as Artificial Base Pairs
Dr. Effi Bätzner, Dr. Yu Liang, Caroline Schweigert, Dr. Andreas-Neil Unterreiner, and Prof. Dr. Hans-Achim Wagenknecht
ChemPhysChem. (2015), 16 (8), 1607-1612, DOI: 10.1002/cphc.201500062 [abstract ]

UV photoexcitation of a dissolved metalloid Ge9 cluster compound and its extensive ultrafast response
M. Klinger, C. Schenk, F. Henke, A. Clayborne, A. Schnepf, A.-N. Unterreiner
Chem. Commun. (2015), 51, 12278-12281, DOI: 10.1039/C5CC04513D [abstract ]

Kinetics of the unimolecular reaction of CH2OO and the bimolecular reactions with the water monomer, acetaldehyde and acetone under atmospheric conditions
Torsten Berndt, Ralf Kaethner, Jens Voigtländer, Frank Stratmann, Mark Pfeifle, Patrick Reichle, Mikko Sipilä, Markku Kulmala, and Matthias Olzmann
Phys. Chem. Chem. Phys. (2015), 17, 19862-19873, DOI: 10.1039/C5CP02224J [abstract ]

Ultrafast Dynamics of o-Nitrophenol: An Experimental and Theoretical Study
Hanna A. Ernst, Thomas J. A. Wolf, Oliver Schalk, Núria González-García, Andrey E. Boguslavskiy, Albert Stolow, Matthias Olzmann, and Andreas-Neil Unterreiner
J. Phys. Chem. A. (2015), 119, 9225-9235, DOI: 10.1021/acs.jpca.5b04900 [abstract ]

Collisional Relaxation of NCN: An Experimental Study with Laser-Induced Fluorescence
Jens Hetzler and Matthias Olzmann
Z. Phys. Chem. (2015), 229, 1503-1519, Open Access DOI: 10.1515/zpch-2015-0673 [abstract ]

Publications 2014

Synthesis and Application of Photolithographically Patternable Deep Blue Emitting Poly(3,6-Dimethoxy-9,9-dialkylsilaflourene)s
Jeffrey J. McDowell, Florian Maier-Flaig, Thomas J. A. Wolf, Andreas-Neil Unterreiner, Uli Lemmer, and Geoffrey Ozin
Appl. Mater. Interfaces (2014), 6, 83-93, DOI: 10.1021/am4025406  [abstract ]

Infrared Detection of Criegee Intermediates Formed during the Ozonolysis of beta-Pinene and Their Reactivity towards Sulfur Dioxide
J. Ahrens, P. T. M. Carlsson, N. Hertl, M. Olzmann, M. Pfeifle, J. L. Wolf,  and T. Zeuch
Angew. Chem. Int. Ed. (2014), 53, 715-719, DOI: 10.1002/anie.201310818  [abstract ]
Angew. Chem. (2014), 126, 733-737, DOI:10.1002/ange.201310818  [abstract ]

Kinetic Analysis of Ethyl Iodide Pyrolysis Based on Shock Tube Measurements
T. Varga, I. Gy. Zsély, T. Turányi, T. Bentz, and M. Olzmann
Int. J. Chem. Kinet. (2014), 46, 295-304, DOI: 10.1002/kin.20829  [abstract ]

Consecutive Chemical Activation Steps in the OH-initiated Atmospheric Degradation of Isoprene: An Analysis with Coupled Master Equations
M. Pfeifle and M. Olzmann
Int. J. Chem. Kinet. (2014), 46, 231-244, DOI: 10.1002/kin.20849  [abstract ]

The Reaction Rates of O2 with Closed-Shell and Open-Shell Alx- and Gax- Clusters under Single-Collision Conditions: Experimental and Theoretical Investigations toward a Generally Valid Model for the Hindered Reactions of O2 with Metal Atom Clusters
Marco Neumaier, Matthias Olzmann, Boggavarapu Kiran, Kit H. Bowen, Bryan Eichhorn, Sarah T. Stokes, Angela Buonaugurio, Ralf Burgert, and Hansgeorg Schnöckel
J. Am. Chem. Soc. (2014), 139 (9), 3607-3616, DOI: 10.1021/ja4125548  [abstract ]

Hexamethylcyclopentadiene: A test case for the combination of time-resolved photoelectron spectroscopy and ab initio multiple spawning simulations
Thomas Jacob Arcangelo Wolf, Thomas Scheby Kuhlman, Oliver Schalk, Todd J. Martínez, Klaus B. Moller, Albert Stolow, and Andreas Unterreiner
Phys. Chem. Chem. Phys. (2014), 16, 11770-11779, DOI: 10.1039/c4cp00977k  [abstract ]

Studying the polymerization initiation efficiency of acetophenone-type initiators via PLP-ESI-MS and femtosecond spectroscopy
Elena Frick, Hanna A. Ernst, Dominik Voll, Thomas J. A. Wolf, Andreas-Neil Unterreiner, and Christopher Barner-Kowollik
Polymer Chemistry (2014), 5, 5053-5068, DOI: 10.1039/c4py00418c [abstract ]

Unraveling the influence of Lanthanide Ions on Intra- and Inter-Molecular Electronic Processes in Fe10Ln10 Nano-Toruses
Amer Baniodeh, Yu Liang, Christopher A. Anson, Nicola Magnani, Annie K. Powell, Andreas-Neil Unterreiner, Simon Seyfferle, Michael Slota, Martin Dressel, Lapo Bogani, and Karin Goß
Advanced Functional Materials (2014), 24 (40), 6280-6290, DOI: 10.1002/adfm.201400336 [abstract ]

Time-resolved photoelectron spectroscopy and ab initio multiple spawning studies of hexamethylcyclopentadiene
T.J.A. Wolf, T.S. Kuhlmann, O. Schalk, T.J. Martínez, K.B. Møller, A. Stolow, A.N. Unterreiner
International Conference on Ultrafast Phenomena (2014), 000-000, DOI: 10.1364/UP.2014.07.Mon.B.5 [abstract ]

Publications 2013

On Ligand Binding Energies in Porphyrinic Systems
Oliver Schalk, Yu Liang, and Andreas-Neil Unterreiner
Z. Phys. Chem. 227 (2013), 35-47, DOI: 10.1524/zpch.2012.0238 [abstract]

The reaction of 2,5-dimethylfuran with hydrogen atoms - An experimental and theoretical study
Philipp Friese, John H. Simmie, and Matthias Olzmann
Proc. Combust. Inst. (2013), 34, 233-239, DOI: 10.1016/j.proci.2012.05.075 [abstract]

Ultrafast photoinduced dynamics of halogenated cyclopentadienes: Observation of geminate charge-transfer complexes in solution
Thomas Jakob Archangelo Wolf, Oliver Schalk, Ronja Radloff, Guorong Wu, Peter Lang, Albert Stolow, and Andreas-Neil Unterreiner
Phys. Chem. Chem. Phys. (2013), 15, 6673-6683, DOI: 10.1039/C3CP44295K [abstract]

The interplay of different relaxation channels in the excited state dynamics of photoinitiators
T. J. A. Wolf, J. Fischer, D. Voll, M. Wegener, C. Barner-Kowollik, and A.-N. Unterreiner
EPJ Web of Conferences (2013), 41, 05008, DOI: 10.1051/epjconf/20134105008 [abstract]

Transient Anisotropy in Degenerate Systems: Experimental Observations in a Cd-porphyrin
Y. Liang, O. Schalk, and A.-N. Unterreiner
EPJ Web of Conferences (2013), 41, 05014, DOI: 10.1051/epjconf/20134105014 [abstract]

Fluorescence Quenching over Short Range in a Donor-DNA-Acceptor System
Dr. Thomas Ehrenschwender, Dr. Yu Liang, Dr. Andreas-Neil Unterreiner, Prof. Dr. Hans-Achim Wagenknecht, Dr. Thomas J. A. Wolf
ChemPhysChem (2013), 14, 1197-1204, DOI: 10.1002/cphc.201200924 [abstract]

Electron tunneling from electronically excited states of isolated bisdisulizole-derived trianion chromophores following UV absorption
Marc-Oliver Winghart, Ji-Ping Yang, Michael Kühn, Andreas-Neil Unterreiner, Thomas J. A. Wolf, Phuong D. Dao, Hong-Tao Liu, Dao-Ling Huang, Wim Klopper, Lai-Sheng Wang, and Manfred Kappes
Phys. Chem. Chem. Phys. (2013), 15, 6726-6736, DOI: 10.1039/C3CP50497B [abstract]

Statistical Rate Theory in Combustion - An Operational Approach
M. Olzmann in:
Development of detailed chemical kinetic models for cleaner combustion (Ed. F. Battin-Leclerc, E. Blurock, J. Simmie) Springer 2013, p.549-576 DOI: 10.1007/978-1-4471-5307-8_21

Ultrafast Dynamics of meso-Tetraphenylmetalloporphyrins: The Role of Dark States
Dr. Yu Liang, Maximillian Bradler, Dr. Melanie Klinger, Dr. Oliver Schalk, Mihaela Carmen Balaban, Prof. Dr. Teodor Silviu Balaban, Prof. Dr. Eberhard Riedle, Dr. Andreas-Neil Unterreiner
ChemPlusChem (2013), 78 (10), 1244-1251, DOI: 10.1002/cplu.201300143 [abstract]

The Reaction of Dimethyl Ether with Hydroxyl Radicals - Kinetic Isostope Effect and Pre-reactive Complex Formation
Cornelie Bänsch, Johannes Kiecherer, Milan Szöri, Matthias Olzmann
J. Phys. Chem. (2013), 117 (35), 8343-8351, DOI: 10.1021/jp405714a [abstract]

Substituent Effects on Dynamics at Conical Intersections: Cycloheptatrienes
Oliver Schalk, Andrey E. Boguslavskiy, Michael S. Schuurman, Rasmus Y. Brogaard, Andreas-Neil Unterreiner, Anna Wrona-Piotrowicz, Nick H. Werstiuk, and Albert Stolow
J. Phys. Chem. A(2013), 117 (40), 10239-10247, DOI: 10.1021/jp309875m [abstract]

Three-dimensional multi-photon direct laser writing with variable repetition rate
Joachim Fischer, Johnathan B. Mueller, Johannes Kaschke, Thomas J.A. Wolf, Andreas-Neil Unterreiner, and Martin Wegener
Optics Express (2013), 21 (22), 26244-26260, DOI: 10.1364/OE.21.026244 [abstract]

On the origin of high transient anisotropies: An exemplification in a Cd-porphyrin
Yu Liang, Melanie Klinger, Oliver Schalk, and Andreas-Neil Unterreiner
J. Chem. Phys. (2013), 139, 224309, DOI: 10.1063/1.4840415 [abstract]

Publications 2012

Elucidating the Early Steps in Photoinitiated Radical Polymerization via Femtosecond Pump-Probe Experiments and DFT Calculations
Thomas J. A. Wolf, Dominik Voll, Christopher Barner-Kowollik, and Andreas-Neil Unterreiner
Macromolecules (2012), 45, 2257-2266, DOI: 10.1021/ma202673q    [abstract]

Kinetics of the NCN + NO Reaction Over a Broad Temperature and Pressure Range
Oliver Welz and Matthias Olzmann
J. Phys. Chem. A. (2012), 116, 7293-7301, DOI: 10.1021/jp303069g    [abstract]

Resonant tunneling through the repulsive Coulomb barrier of a quadruply charged molecular anion
Phuong Diem Dau, Hong-Tao Liu, Ji-Ping Yang, Marc-Oliver Winghart, Thomas J. A. Wolf, Andreas-Neil Unterreiner, Patrick Weis, Yu-Run Mioa, Chuan-Gang Ning, Manfred M. Kappes, and Lai-Sheng Wang
Phys. Rev. A (2012), 85, 064503, DOI: 10.1103/PhysRevA.85.064503    [abstract]

Publications 2011

The reaction of iso-propyl radicals with oxygen atoms - rate coefficient, product branching, and relevance for combustion modeling
K. Hoyermann, M. Olzmann, O. Welz, T. Zeuch
Proc. Combust. Inst. (2011), 33, 283-291, DOI: 10.1016/j.proci.2010.05.075    [abstract]

High-temperature kinetics of propyne and allene: Decomposition vs. isomerization
B. R. Giri, R. X. Fernandes, T. Bentz, H. Hippler, M. Olzmann
Proc. Combust. Inst. (2011), 33, 267-272, DOI: 10.1016/j.proci.2010.05.072    [abstract]

Experimental and Theoretical Investigation of the Kinetics of the Reaction of Atomic Chlorine with 1,4-Dioxane
B. R. Giri, J. M. Roscoe, N. Gonzáles-García, M. Olzmann, J. M. H. Lo, R. A. Marriot
J. Phys. Chem. A(2011), 115, 5105-5111, DOI: 10.1021/jp201803g    [abstract]

The phenyl + phenyl reaction as pathway to benzynes : An experimental and theoretical study
S. H. Dürrstein, M. Olzmann, J. Aguilera-Iparraguirre, R. Barthel, W. Klopper
Chem. Phys. Lett. (2011), 513, 20-26, DOI: 10.1016/j.cplett.2011.07.050    [abstract]

Pump-probe spectroscopy on photoinitiators for stimulated-emission-depletion optical lithography
Thomas J. A. Wolf, Joachim Fischer, Martin Wegener, Andreas-Neil Unterreiner
Opt. Lett. (2011), 36, 3188-3190, DOI: 10.1364/OL.36.003188    [abstract]

Transient anisotropy in degenerate systems: A semi-classical approach
Oliver Schalk, Andreas-Neil Unterreiner
Z. Phys. Chem. (2011), 225, 927-938, DOI: 10.1524/zpch.2011.0133    [abstract]

Relaxation dynamics of Electronically Excited C60- in o-Dichlorobenzene and Tetrahydrofuran Solution
Helge Brands, O. T. Ehrler, M. Kappes, Andreas-Neil Unterreiner
Z. Phys. Chem. (2011), 225, 939-956, DOI: 10.1524/zpch.2011.0137    [abstract]

Pyrolysis of Ethyl Iodide as Hydrogen Atom Source: Kinetics and Mechanism in the Temperature Range 950 - 1200 K
Tobias Bentz, Milan Szõri, Bela Viskolcz, Matthias Olzmann
Z. Phys. Chem. (2011), 225, 1117-1128, DOI: 10.1524/zpch.2011.0178    [abstract]

Ultrafast Dynamics of the First Excited State of Quasi Monodispersed Single-Walled (9,7) Carbon Nonotubes
Frank Hennrich, Manfred M. Kappes, Melanie Klinger, Andreas-Neil Unterreiner
J. Phys. Chem. C (2011), 115, 23711-23717, DOI: 10.1021/jp2075176    [abstract]

Novel Lanthanide-Based Polymeric Chains and Corresponding Ultrafast Dynamics in Solution
Dominique T. Thielemann, Melanie Klinger, Thomas J. A. Wolf, Yanhua Lan, Wolfgang Wernsdorfer, Madleen Busse, Peter W. Roesky, Andreas-Neil Unterreiner, Annie K. Powell, Peter C. Junk, Glen B. Deacon
Inorg. Chem. (2011), 50, 11990-12000, DOI: 10.1021/ic201157m    [abstract]

Competing Channels in the Propene + OH Reaction: Experiment and Validated Modelling over a Broad Temperature and Pressure Range
Claudia Kappler, Judit Zádor, Oliver Welz, Ravi X. Fernandez, Matthias Olzmann, Craig A. Taatjes
Z. Phys. Chem (2011), 225, 1-21, DOI: 10.1524/zpch.2011.0165    [abstract]